Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube     

杨培芳  吴锋民  滕波涛  刘莎  蒋健中 《海洋学报(英文版)》2010,29(9)

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.  相似文献   

Subsoil zoning of Mexico City using qualitative relationships between soil strength and electrical resistivity     

Mario Benhumea Leon 《Geotechnical and Geological Engineering》1989,7(1):59-68

Summary The seismic events occurring on 19 and 20 September 1985, whose epicentre was located in the coastal region of Michoacan, Mexico, produced tremendous damage in Mexico City. As a result of these losses the civil authorities of the city decided to study and evaluate the mechanical characteristics of the subsoil. To achieve this, it was necessary to drill several boreholes to obtain needed geophysical and geotechnical information. The geophysical method of electrical resistivity was the most appropriate to the research. This method enabled us to understand the structure and soil characteristics of the Mexican Valley.  相似文献   

未来地震震级的定量计算   总被引：1，自引：0，他引：1  

蔡静观  刘正荣 《地震研究》1989,(3)

将某一地震带在强震前某一时期内发生的地震,按其面波震级大小自大到小排列,并以N=2、3、4、……来累计频度,采用公式logN=a-bM计算a、b,从而计算出第一个地震的震级M_1,这就是未来可能发生地震的震级。通过对川滇地区和华北地区的九次近期强震进行计算,结果表明,在震级测定误差范围(±0.3级)内,上述的M和logN之间具有很好的线性关系,这就为地震预报和地震区划中定量计算未来地震震级提出了一个新的方法。  相似文献   

A garnet population in Yellowknife schist, Canada   总被引：6，自引：0，他引：6  

R. KRETZ 《Journal of Metamorphic Geology》1993,11(1):101-120

Abstract Data are presented on a garnet population in a specimen of garnet-biotite-plagioclase-quartz schist from the cordierite zone of an Archaean thermal dome in the Southern Slave Province of the Canadian Shield. Garnet crystals are bounded by planar dodecahedral faces and by trapezohedral faces which on the 10-μm scale are corrugated. Crystal distribution, as revealed by dissection of a small cubic volume of rock, is random. The size distribution is normal, with a mean diameter of 0.81 mm and a standard deviation of 0.32 mm. In the largest crystal of the population (mean radius 0.83 mm), [Mn] = 100 Mn/(Fe + Mg + Mn + Ca) decreases from 14.5 at the centre to 7.5 and then increases in the outer margin to 8.5; [Fe] increases continuously from 67 at the centre to 77 at the surface; [Mg] increases from 12.5 to 13.5 and then falls sharply to 11; [Ca] remains unchanged at 4.0 and then drops to 3.3. Progressively smaller crystals have progressively lower [Mn] and higher [Fe] concentrations at their centres, while all crystals have the same margin composition. Growth vectors extending from given concentration contours to crystal surfaces are of equal length regardless of the size of the crystal in which the vector is located. A garnet-forming model is presented in which reaction was initiated by a rise in temperature. Nucleation sites were randomly selected. The nucleation rate increased with time and then declined. Crystal faces advanced at a constant linear rate, which implies an increase in volume proportional to surface area. Initially, the composition of garnet deposited on crystal surfaces was determined by van Laar equations of equilibrium, which demanded the withdrawal of Mn and Fe from within chlorite crystals. This transfer reaction was then accompanied by an ion exchange reaction which moved Mn and Fe to garnet surfaces from biotite, in exchange for Mg. The exchange reaction provides an explanation for the high overall concentration of Mn and Fe in garnet and for the observed Mn and Mg reversals in the margins of crystals. The increase of garnet volume in the garnet population is found to be parabolic, i.e. Vαα⁵.  相似文献   

多源信息方法在殷庄矿开采水文地质预测分区中的应用     

赵林  吴大新  郑世书  徐志斌  孙亚军 《吉林大学学报(地球科学版)》1994,(2)

根据对殷庄矿地质、水文地质、开采条件与矿井涌水之间关系的研究，提出了煤矿开采水文地质条件预测分区的方法——多源信息方法。该方法借助于地理信息系统技术实现了矿井涌水因素间的有机处理。经过将模型与实际情况反复拟合，最终得出了分区预测模型。  相似文献   

宝山铜钼多金属矿田矿化分带和蚀变组合特征     

李荣清 《湖南地质》1990,(2)

宝山多金属矿田的矿化产于下石炭统石磴子组灰岩中。以宝岭倒转背斜轴为核心,矿田中部是由矽卡岩型铜钼矿床红组成的铜钼矿带,向外是由多个铅锌银矿床组成的铅锌跟矿带。笔者通过铜钼矿石和东部铅锌银矿石的化学成分,矿物组合及黄铁矿、黝铜矿的标型特征,探讨了宝山多金属矿田的矿化及蚀变组合分分带,并以此作为同类型矿床的找矿标志。  相似文献   

On the interpretation of peak metamorphic temperatures in light of garnet diffusion during cooling   总被引：13，自引：0，他引：13  

F. S. SPEAR 《Journal of Metamorphic Geology》1991,9(4):379-388

Abstract Finite difference models of Fe-Mg diffusion in garnet undergoing cooling from metamorphic peak conditions are used to infer the significance of temperatures calculated using garnet-biotite Fe-Mg exchange thermometry. For rocks cooled from high grades where the garnet was initially homogeneous, the calculated temperature (T_calc) using garnet core and matrix biotite depends on the size of the garnet, the ratio of garnet to biotite in the rock (V_garnet/V_biotite) and the cooling rate. For garnets with radii of 1 mm and V_garnet/V_biotite<1, T_calc is 633, 700 and 777°C for cooling rates of 1, 10 and 100°C/Ma. For V_garnet/V_biotite= 1 and 4 and a cooling rate of 10° C/Ma, T_calc is approximately 660 and 610° C, respectively. Smaller and larger garnets have lower and higher T_calc, respectively. These results suggest that peak metamorphic temperatures may be reliably attained from rocks crystallized at conditions below T_calc of the garnet core, provided that V_garnet/V_biotite is sufficiently small (<0.1) and that the composition of the biotite at the metamorphic peak has not been altered during cooling. Numerical experiments on amphibolite facies garnets with nominal peak temperatures of 550–600° C generate a ‘well’in Fe/(Fe + Mg) near the rim during cooling. Maximum calculated temperatures for the assemblage garnet + chlorite + biotite + muscovite + plagioclase + quartz using the Fe/(Fe + Mg) at the bottom of the ‘well’with matrix biotite range from 23–43° C to 5–12° C below the peak metamorphic temperature for cooling rates of 1 and 100° C/Ma, respectively. Maximum calculated temperatures for the assemblage garnet + staurolite + biotite + muscovite + plagioclase + quartz are approximately 70° C below the peak metamorphic temperature and are not strongly dependent on cooling rate. The results of this study indicate that it may be very difficult to calculate peak metamorphic temperatures using garnet-biotite Fe-Mg exchange thermometry on amphibolite facies rocks (T_max > 550° C) because the rim composition of the garnet, which is required to calculate the peak temperature, is that most easily destroyed by diffusion.  相似文献   

重熔斑岩型锡多金属矿床地质特征及成矿模式   总被引：1，自引：0，他引：1  

张国林 《矿产与地质》1991,5(4):249-261

对重熔斑岩型锡多金属矿床成矿岩体的岩石类型、岩体形态、规模、岩石化学、微量元素和稀土元素地球化学、矿物包裹体和稳定同位素地球化学特征等方面进行了较系统的研究;并对该类矿床的矿化、蚀变分带特征和矿化与蚀变带的关系作了论述,指出了该类矿床最重要的蚀变带为黄玉云英岩化带, 在详细研究该类矿床的基础上,建立了重熔斑岩型锡多金属矿床的成矿模式.  相似文献   

Binomial model on seismic risk analysis     

王健  时振梁 《地震学报(英文版)》1994,(Z1)

ＢｉｎｏｍｉａｌｍｏｄｅｌｏｎｓｅｉｓｍｉｃｒｉｓｋａｎａｌｙｓｉｓＪｉａｎＷＡＮＧ（王健）ａｎｄＺｈｅｎ－ＬｉａｎｇＳＨＩ（时振梁）（ＩｎｓｔｉｔｕｔｅｏｆＧｅｏｐｈｙｓｉｃｓ，ＳｔａｔｅＳｅｉｓｍｏｌｏｇｉｃａｌＢｕｒｅａｕ，Ｂｅｉｊｉｎｇ１００...  相似文献   

首都圈地区地震活动的分期与分区研究     

孙士宏 《地震》1994,(6):19-25

本文通过对首都圈地区（北纬３８．５°至４１．０°，东经１１３．０°至１２０．０°）公元１５００年以来Ｍ≥５地震的系统分析，并应用７０年代以来所取得的该地区最新地球物理场的有关资料进行分区后，发现该地区５级以上地震存在较明显的成组发生及有１１年的时段性特征，且每一组的活动具有地区性特征。这一现象对首都圈地区５级以上的地震的监视预报具有一定的意义。  相似文献